Some says it is redox and some say it is bunsen… what is the principle … any one please explain in brief… Thanq in advance
This Classic method referenced but…
Karl Fischer titration is a coulometric or volumetric titration to determine trace amounts of water in a sample.
B·I2 + B·SO2 + B + H2O → 2BH+I− + BSO3
BSO3 + ROH → BH+ROSO3−
volumetric titration the same principles as the coulometric titration except that the anode solution above ( B·SO2) now is used as the titrant solution. The titrant consists of an alcohol (ROH), base (B), SO2 and a known concentration of I2.